Please use this identifier to cite or link to this item: https://doi.org/10.1021/nn900811t
Title: Nonlocal chemical reactivity at organic - Metal interfaces
Authors: Chen, L. 
Li, H.
Wee, A.T.S. 
Keywords: Chemical reactions
Electron transport
Interface
Scanning tunneling microscopy
Surface
Issue Date: 24-Nov-2009
Citation: Chen, L., Li, H., Wee, A.T.S. (2009-11-24). Nonlocal chemical reactivity at organic - Metal interfaces. ACS Nano 3 (11) : 3684-3690. ScholarBank@NUS Repository. https://doi.org/10.1021/nn900811t
Abstract: Understanding electron transport at the organic-inorganic interface is crucial for many research fields including surface physics and chemistry. In this article, we report the nonlocal chemical reactivity of one monolayer copper hexadecafluorophthalocyanine (F16CuPc) adsorbed on two different substrates, Ag(111) and Au(111), by injecting hot electrons from a scanning tunneling microscope tip. On the basis of experimental and theoretical results, the nonlocal reactions are proposed to strongly depend on hot-electron transport through molecule-substrate interface states. This observation of nonlocal reactivity increases our understanding of electron transport at organic-metal interfaces. © 2009 American Chemical Society.
Source Title: ACS Nano
URI: http://scholarbank.nus.edu.sg/handle/10635/115206
ISSN: 19360851
DOI: 10.1021/nn900811t
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

32
checked on Dec 12, 2018

WEB OF SCIENCETM
Citations

33
checked on Dec 12, 2018

Page view(s)

56
checked on Oct 19, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.