Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/112079
Title: Solid-state thermolysis of trans-diamminenickel(ii) catena-tetra-μ-cyanonickelate(II)clathrates and their degradation intermediates
Authors: Hor, T.S.A. 
Chan, H.S.O. 
Lee, H.K. 
Doshi, S.D.
Leong, Y.-P.
Lian, W.-T.
Phang, L.-T.
Sim, M.-M. 
Tan, M.-M.
Issue Date: 30-Sep-1990
Citation: Hor, T.S.A.,Chan, H.S.O.,Lee, H.K.,Doshi, S.D.,Leong, Y.-P.,Lian, W.-T.,Phang, L.-T.,Sim, M.-M.,Tan, M.-M. (1990-09-30). Solid-state thermolysis of trans-diamminenickel(ii) catena-tetra-μ-cyanonickelate(II)clathrates and their degradation intermediates. Thermochimica Acta 167 (1) : 57-64. ScholarBank@NUS Repository.
Abstract: The solid state decomposition of Ni(CN)2(NH3)(G)n (or strictly, Ni(NH3)2Ni(CN)4· 2nG) where G = aniline, benzene and phenol, has been monitored by infrared spectroscopy, and thermogravimetric (TG) and differential scanning calorimetric analyses. The inclusion ratio, n, which can be conveniently obtained from the thermal profiles, follows the order C6H5NH2 /s C6H5OH /s C6H6. The step-wise degradation of these clathrates has been followed by TG and modelling experiments in Schlenk flasks. All the decompositional intermediates have been isolated and identified by TG, IR and microanalyses. © 1990.
Source Title: Thermochimica Acta
URI: http://scholarbank.nus.edu.sg/handle/10635/112079
ISSN: 00406031
Appears in Collections:Staff Publications

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